Photochromism of diarylethene molecules and crystals

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Photochromism of diarylethene molecules and crystals

Photochromism is defined as a reversible transformation of a chemical species between two isomers upon photoirradiation. Although vast numbers of photochromic molecules have been so far reported, photochromic molecules which exhibit thermally irreversible photochromic reactivity are limited to a few examples. The thermal irreversibility is an indispensable property for the application of photoc...

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Invisible photochromism of diarylethene derivatives.

Diarylethene derivatives with oxidized thiophene rings shift their absorption band to a shorter wavelength in the UV region upon photocyclization; no color change was observed during the photochromic reaction, and the invisible photochromism is advantageous for devices used under room light.

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Photochromism in sound-induced alignment of a diarylethene supramolecular nanofibre.

A photochromic supramolecular nanofibre, composed of a diarylethene derivative, exhibits hydrodynamic alignment upon exposure to the audible sound. The aligned nanofibre outputs linear dichroism (LD), whose wavelength region can be switched reversibly with UV and visible light.

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Light-driven bending of diarylethene mixed crystals.

Mixed crystals composed of 1,2-bis(2-methyl-5-(p-methoxyphenyl)-3-thienyl)perfluorocyclopentene (1a) and 1,2-bis(5-methyl-2-(p-methoxyphenyl)-4-thiazolyl)perfluorocyclopentene (2a) were prepared, and their photochromic as well as light-driven bending performance was studied to reveal how shape changes of individual molecules cause the bending response. 1a and 2a molecules, having similar geomet...

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Photochromism and molecular logic gate operation of a water-compatible bis-glycosyl diarylethene.

We report the synthesis of a water-compatible bis-glycosyl diarylethene using click chemistry that undergoes photochromism and functions as a molecular logic gate.

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ژورنال

عنوان ژورنال: Proceedings of the Japan Academy, Series B

سال: 2010

ISSN: 0386-2208,1349-2896

DOI: 10.2183/pjab.86.472